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By Matthias J.N.Junk

In his thesis, Matthias Junk takes an leading edge method of examine the neighborhood constitution and dynamics of organic and artificial amphiphilic macromolecules in a position to transporting small molecules. changing the latter with strong radicals, he makes use of cutting-edge electron paramagnetic resonance (EPR) spectroscopy to explain the hugely appropriate shipping functionality from the point of view of the visitor molecules. Such, he demonstrates that the sensible constitution of human serum albumin in answer considerably differs from its crystal constitution – a end result of the protein’s adaptability to host a variety of endogenous compounds and drug molecules. additional, he exhibits that the thermal cave in of thermoresponsive hydrogels and dendronized polymers results in static and dynamic heterogeneities at the nanoscale. those heterogeneities endure effects for the material’s internet hosting homes and let unexpected advanced catalytic functionalities.

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